What the statewide pattern says
Fast limestone under farms and subdivisions
West Virginia's documented nitrate sits in the eastern panhandle karst — Great Valley limestone under orchards, poultry and Washington-commuter growth, studied by USGS since the 1960s.
The eastern panhandle is one of the longest-studied karst aquifers in the country. USGS sampling in Jefferson County found 14 percent of 192 wells at or above the 10 mg/L federal limit in 1981; a decade later the follow-up found 26 percent of wells and springs over the limit, with fecal bacteria at half the sites (Kozar, 2002 — USGS karst investigations synopsis). Dye tracing showed why: groundwater there moves 70 to 840 feet per day along bedding, so a sinkhole or septic field connects to a well in days.
The driving land uses are agriculture and growth together — orchards and poultry in the Great Valley, plus one of the fastest Washington-commuter build-outs in the state on individual wells and septic. Berkeley County's karst work found bacteria the bigger problem and nitrate patchier; Jefferson carries the nitrate signature (USGS SIR 2016-5048).
The Ohio River corridor counties — Mason, Jackson, Wood — form the map's second, thinner cluster on alluvial and fractured-rock ground. The published nitrate literature there is thin, so this page marks the readings without claiming a certified source. About 90 percent of West Virginia's rural population drinks groundwater (USGS Fact Sheet 48-95).
The supported source reading is agricultural and septic nitrogen on fast karst in the panhandle — not a certified source at any individual system (Nolan and Hitt, 2006).