What the statewide pattern says
Two Washingtons for nitrate
Washington's higher nitrate splits by geology: fractured-basalt and basin-fill aquifers under irrigation in the Columbia Basin, and permeable glacial outwash under mixed farm and suburban land around Puget Sound.
East of the Cascades, the Columbia Basin is the documented core. The aquifers — layered flood basalt with sediment interbeds — are highly vulnerable: permeable basalt interflow zones and the irrigation-recharge layer move nitrate readily, regionally into deep supply wells. USGS found nitrate above the federal limit in about 20 percent of Columbia Plateau wells (Rupert and others, 2014), and in the Adams–Franklin–Grant Groundwater Management Area, about 20 percent of drinking-water wells have exceeded the limit in a region that draws more than 80 percent of its drinking water from groundwater (USGS Washington Water Science Center).
The source work there is unusually direct: in the GWMA, the strongest correlates of nitrate above 3 mg/L were fertilizer application and well depth, and irrigated agricultural areas carried the highest predicted risk. Trend analysis found concentrations locally elevated but roughly stable to declining in the early 2000s (Frans and Helsel, 2005). The supported source reading in the east is agricultural — irrigated-cropland fertilizer. The Lower Yakima Valley carries a parallel designation, and the Spokane Valley–Rathdrum Prairie aquifer adds a very permeable glacial-outwash setting in the far east.
West of the Cascades the mechanism differs. The Puget Sound lowlands sit on permeable glacial outwash, and USGS susceptibility modeling there tied elevated nitrate to fertilizer use and septic-system density over unconfined outwash (Tesoriero and Voss, 1997) — matching the map's western footprint in Thurston, Pierce and Island counties. The supported western reading is mixed fertilizer and septic on permeable outwash. Neither reading certifies a source at an individual system (Nolan and Hitt, 2006).