What the statewide pattern says
Irrigated plains, oxidizing aquifers, and nitrate that stays nitrate
Colorado's elevated systems concentrate in the South Platte alluvial corridor — Weld, Logan, Sedgwick, Phillips — and the High Plains irrigation counties of the east, with a Front Range cluster in El Paso and Jefferson on alluvial and Denver Basin aquifers.
Colorado's 78 mapped systems above the natural-background band draw two features: the South Platte River corridor from Weld through Logan, Sedgwick and Phillips, and the High Plains irrigation counties — Kit Carson, Cheyenne, Lincoln, Baca — plus a Front Range cluster in El Paso and Jefferson and a mountain scatter led by Teller. Nearly 5 percent of the state's reporting systems sit at or above 3.00 mg/L.
The South Platte alluvial aquifer is where American nitrate science grew up. USGS work near Greeley documented nitrogen loading from irrigated crops and poultry farms directly into the alluvium (Gaggiani, USGS), and McMahon and Böhlke's studies of denitrification and mixing in the stream–aquifer system became the national reference for how nitrate moves, mixes and occasionally breaks down along an irrigation river (Colorado Geological Survey bibliography).
The eastern plains' vulnerability is quantified. USGS modeled the High Plains aquifer's recently recharged groundwater from 336 wells — median nitrate 3.82 mg/L, 48 percent of samples above 4 mg/L, 13 percent above the 10 mg/L federal limit — and found vulnerability tracks the percentage of agricultural land, shallow depth to water, and low clay and organic matter in the unsaturated zone; the aquifer's oxidizing conditions give denitrification little chance (USGS SIR 2006-5050).
The honest gap: the Front Range and mountain clusters — El Paso, Teller, Jefferson — mix alluvial, Denver Basin and fractured-bedrock settings with septic growth, but dedicated county nitrate studies for them are thin; this page reads their setting only. The supported source reading is irrigated-agriculture nitrogen on the South Platte alluvium and the High Plains; mixed and setting-only along the Front Range — not a certified source at any individual system (Nolan and Hitt, 2006).